The shots from the Scatter Lasers happen simultaneously as the shots from the star cannons. The Greater Demon is not a viable target for that because he appears after the shooting from the war walkers happens. Now, As far as i know, the War walkers all have to fire at the same target so the Greater Demon is not a viable target.
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Hallowed are the Ori.
Hallowed are the children of the Ori.
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Those who seek the path to enlightenment must not be led astray!
Believe in the truth of all things and you too may find the path to enlightenment.
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Those who abandon the path are evil.
Those who reject the path to enlightenment, must be destroyed.
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