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Old 06-15-2007   #10 (permalink)
Icarus Athrasuriel
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I feel like expanding, scientifically, on the whole methane subject.

CH4, methane, is the simplest alkane. It is made up of one carbon atom and four hydrogen atoms. When burned in the presence of oxygen, one molecule of methane produces one molecule of CO2 (Carbon Dioxide), through the chemical process:

CH4 + O2 → CO2

Leaving 4 Hydrogen atoms. These react with the oxygen to create two H2O (Water) molecules through the chemical process:

4H + O2 → 2H2O

In addition, methane is also 97% of what makes up natural gas, At room temperature and standard pressure, methane is a colorless, odorless gas; the smell characteristic of natural gas is an artificial safety measure caused by the addition of an odorant, often methanethiol or ethanethiol.

Methane has a boiling point of −182.6 C at a pressure of one atmosphere. As a gas it is flammable only over a narrow range of concentrations (5–15%) in air. Liquid methane does not burn unless subjected to high pressure (normally 4–5 atmospheres.)

Methane is not toxic; however, it is highly flammable and may form explosive mixtures with air. Methane is violently reactive with oxidizers, halogens, and some halogen-containing compounds. Methane is also an asphyxiant and may displace oxygen in an enclosed space. Asphyxia may result if the oxygen concentration is reduced to below 19.5% by displacement. The concentrations at which flammable or explosive mixtures form are much lower than the concentration at which asphyxiation risk is significant.

In the combustion of methane, several steps are involved:

Methane is believed to form a formaldehyde (HCHO or H2CO). The formaldehyde gives a formyl radical (HCO), which then forms carbon monoxide (CO). The process is called oxidative pyrolosis:

CH4 + O2 → CO + H2 + H2O

Following oxidative pyrolysis, the H2 oxidizes, forming H2O, replenishing the active species, and releasing heat. This occurs very quickly, usually in significantly less than a millisecond.

2H2 + O2 →2H2O

Finally, the CO oxidizes, forming CO2 and releasing more heat. This process is generally slower than the other chemical steps, and typically requires a few to several milliseconds to occur.

2CO + O2 →2CO2
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Last edited by Icarus Athrasuriel; 06-15-2007 at 09:23 AM.
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